技术骨干

李龙

更新时间:2021-03-03  浏览量:

一、导师简介:

96FEB

李龙,男,教授,硕导, longwzu1990@wzu.edu.cn

2012.9-2018.6博士就读于厦门大学化学化工学院(导师:叶龙武教授)。2018.6-2019.6在厦大做研究助理。2019.6-2020.6在德国马尔堡大学做博士后研究(导师:Eric Meggers 教授)。于2020.9受温州大学绿色通道资助进入温州大学化学材料学院工作。研究兴趣主要在于有机方法学研究,以通讯作者,第一作者身份在 J. Am. Chem. Soc.,Angew. Chem. Int. Ed.,ACS Catal.,Chem. Sci.等国际著名刊物上发表正式论文26篇,论文被引用700余次(H-index: 16, 其中2篇研究论文单篇被引>100次, 部分文章被选为front cover, ESI高被引论文。

二、研究方向:

1.炔烃转化

2.新型手性催化剂的设计与应用

3.不对称催化合成手性功能分子

三、发表文章:

1. Enantioselective Rh-Catalyzed Azide-Internal-Alkyne Cycloaddition for Construction of Axially Chiral 1,2,3-Triazoles.Wen-Ting Guo, Bo-Han Zhu, Yi Chen, Jian Yang, Peng-Cheng Qian,* Chao Deng,*Long-Wu Ye, andLong Li*.J. Am. Chem. Soc.2022, 144,6981.


2. Auxiliary-Free Remote Dearomatizative Nitrenoid Transfer for Enantioselective Constructionof Spirolactams.Bo-Han Zhu, Wen-Ting Guo, Qing Sun, * Peng-Cheng Qian, * Long-Wu Ye, andLong Li*,Adv. Synth. & Catal.2022,364, 314.

3. Claisen Rearrangement Triggered by Brønsted Acid-Catalyzed Alkyne Alkoxylation.Yao-Hong Yan,Long Li,*Long-Wu Ye,* Synlett 2022, accepted.

4. Recent Progress in the Gold-Catalyzed Annulations of Ynamides with Isoxazole Derivatives via α-Imino Gold Carbenes.Long Li,*Wen-Feng Luo, Long-Wu Ye,* Synlett2021,32, 1303.

5. Regio- and diastereoselective synthesis of trans-3,4-diaryldihydrocoumarins via metal-free [4+2] annulation ofynamideswith o-hydroxybenzyl alcohols.Wen-Feng Luo, Long-Wu Ye,Long Li*and Peng-Cheng Qian*,Chem. Commun.,2021,57, 5032.

6. Claisen rearrangement triggered by transition metal-catalyzed alkyne alkoxylation.Chong-Yang Shi,Long Li,* Wei Kang, Yan-Xin Zheng, Long-Wu Ye,*Coord. Chem. Rev.2021, 446, 214131.

7. Completing Pyridine-2,6-bis(oxazoline) with Cyclometalated Ligand for Modulated Asymmetric Transition Metal Catalysis.Long Li,† Feng Han,† Xin Nie,† Yubiao Hong, Sergei Ivlev and Eric Meggers,*Angew. Chem. Int. Ed.2020, accepted.

8. Zinc-Catalyzed Alkyne Oxidation/C−H Functionalization: Highly Site-Selective Synthesis of Versatile Isoquinolones and β-Carbolines.Long Li,† Bo Zhou,† Yong-Heng Wang, Chao Shu, Yi-Fei Pan, Xin Lu,* Long-Wu Ye,*Angew. Chem. Int. Ed.2015,54, 8245.

9. Metal-Free Alkene Carbooxygenation Following Tandem Intramolecular Alkoxylation/Claisen Rearrangement: Stereocontrolled Access to Bridged [4.2.1] Lactones.Long Li,Xin-Qi Zhu, Ying-Qi Zhang, Hao-Zhen Bu,Peng Yuan, Jinyu Chen, Jingyi Su, Xianming Deng, Long-Wu Ye,*Chem. Sci.2019,10, 3123-3129.

10. Generation of Gold Carbenes in Water: Efficient Intermolecular Trapping of the α-Oxo Gold Carbenoids by Indoles and Anilines.Long Li,† Chao Shu,Bo Zhou, Yong-Fei Yu, Xin-Yu Xiao, Long-Wu Ye,*Chem. Sci.2014,5, 4057.

11. Reversal of Regioselectivity in Catalytic Arene-Ynamide Cyclization: Direct Synthesis of Valuable Azepino[4,5-b]indoles and β–Carbolines and DFT Calculations.Long Li, Xiu-Mei Chen, Ze-Shu Wang, Bo Zhou, Xin Liu, Xin Lu,* Long-Wu Ye,*ACS Catal.2017,7, 4004.

12. Recent Advances in Transition-Metal-Catalyzed Reactions of Alkynes with Isoxazoles.Long Li,† Tong-De Tan,† Ying-Qi Zhang, Xin Liu, Long-Wu Ye,*Org. Biomol. Chem.2017,15, 8483.

13. Yttrium-Catalyzed Tandem Intramolecular Hydroalkoxylation/Claisen Rearrangement: Efficient Synthesis of Medium-Sized Lactams. Bo Zhou,Long Li, Xin-Qi Zhu, Juan-Zhu Yan, Yi-Lin Guo, Long-Wu Ye,*Angew. Chem. Int. Ed.2017,56, 4015.

14. Flexible and Practical Synthesis of 3-Oxyindoles through Gold-Catalyzed Intermolecular Oxidation ofo-Ethynylanilines. Chao Shu,Long Li, Xin-Yu Xiao, Yong-Fei Yu, Yi-Fan Ping, Jin-Mei Zhou, Long-Wu Ye,*Chem. Commun.2014,50, 8689.

15. Gold-Catalyzed Intermolecular Oxidation of Chiral Homopropargyl Sulfonamides: A Reliable Access to Enantioenriched Pyrrolidin-3-ones. Chao Shu,Long Li, Yong-Fei Yu, Shuang Jiang, Long-Wu Ye,*Chem. Commun.2014,50,2522.

16. Divergent Synthesis of N-Heterocycles via Controllable Cyclization of Azido-Diynes Catalyzed by Copper and Gold. Wen-Bo Shen, Qing Sun,Long Li,Xin Liu, Bo Zhou, Juan-Zhu Yan, Xin Lu,* Long-Wu Ye,*Nat. Commun.2017,8, 1748.

四、获奖情况:

1. 2018年,第十三届福建省自然科学优秀学术论文一等奖 (全省共33位)

2. 2018年,厦门大学优秀毕业论文奖

3. 2015年,唐敖庆奖学金 (全国共42位)

4. 2014年,教育部硕士国家奖学金

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